What Episode Does Usopp First Use Haki. The sniper of the Straw Hat Pirates Usopp tapped into the power of Haki only recently during the Dressrosa arc of One Piece. After being separated in the sabaody archipeology.
Answer 1 of 5. 12-15 and Episode 516 Rayleigh explains Haki. Conquerors is essentially the user enforcing their strong will onto an opponent.
He is the fourth member of the crew and the third to join doing so at the end of the Syrup Village Arc.
He is the fourth member of the crew and the third to join doing so at the end of the Syrup Village Arc. Although it is unknown if he can use it Sanji does know about Haoshoku Haki something he along with the rest of the crew had not shown any knowledge of during the first half of the series. The crew members end up in various conflicts and scenarios with even Nami and Usopp confronting an imposter Straw Hat. Based on the series own internal logic the only explanation for Zoros ability to cut steel and stone is the unconscious unpolished application of Armament Haki.